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Isothermal processes are of special interest for ideal gases. This is a consequence of Joule's second law which states that the internal energy of a fixed amount of an ideal gas depends only on its temperature. [4] Thus, in an isothermal process the internal energy of an ideal gas is constant. This is a result of the fact that in an ideal gas ...
Isotherm (contour line) – a type of equal temperature at a given date or time on a geographic map. Isotherm – in thermodynamics, a curve on a P-V diagram for an isothermal process. Moisture sorption isotherm – a curve giving the functional relationship between humidity and equilibrium water content of a material for a constant temperature.
Moisture sorption isotherm. At equilibrium, the relationship between water content and equilibrium relative humidity of a material can be displayed graphically by a curve, the so-called moisture sorption isotherm. For each humidity value, a sorption isotherm indicates the corresponding water content value at a given, constant temperature.
Freezing level. The freezing level, or 0 °C (zero-degree) isotherm, represents the altitude in which the temperature is at 0 °C (the freezing point of water) in a free atmosphere (i.e. allowing reflection of the sun by snow, icing conditions, etc.). Any given measure is valid for only a short period of time, often less than a day as ...
The Freundlich isotherm is the most important multi-site adsorption isotherm for rough surfaces. =, where α F and C F are fitting parameters. This equation implies that if one makes a log–log plot of adsorption data, the data will fit a straight line. The Freundlich isotherm has two parameters, while Langmuir's equations has only one: as a ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas cannot be liquefied by pressure ...
Van der Waals equation. The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance).
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